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Interfacial energies of systems of chiral molecules

Braides A.
•
Garroni A.
•
Palombaro M.
2016
  • journal article

Periodico
MULTISCALE MODELING & SIMULATION
Abstract
We consider a simple model for the assembly of chiral molecules in two dimensions driven by maximization of the contact area. We derive a macroscopic model described by a parameter taking nine possible values corresponding to the possible minimal microscopic patterns and modulated phases of the chiral molecules. We describe the overall behavior by means of an interaction energy of perimeter type between such phases. This energy is a crystalline perimeter energy, highlighting preferred directions for the interfaces between ensembles of molecules labeled by different values of the parameter.
DOI
10.1137/15M104894X
WOS
WOS:000388444300004
Archivio
https://hdl.handle.net/20.500.11767/139498
info:eu-repo/semantics/altIdentifier/scopus/2-s2.0-84989338125
https://arxiv.org/abs/1512.01123
https://ricerca.unityfvg.it/handle/20.500.11767/139498
Diritti
metadata only access
Soggetti
  • Chiral molecules

  • Crystalline energies

  • Interfacial energies

  • Lattice systems

  • Wulff shapes

  • γ-convergence

  • Settore MAT/05 - Anal...

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