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Mechanical pulling of linked ring polymers: Elastic response and link localisation

Caraglio, Michele
•
Micheletti, Cristian
•
Orlandini, Enzo
2017
  • journal article

Periodico
POLYMERS
Abstract
By using Langevin dynamics simulations, we study how semiflexible rings that are topologically linked respond tomechanical stretching.We use both constant-force and constant-velocity pulling protocols and map out how the mechanical tension affects observables related to metric quantities such as the longitudinal extension or span, and topology-related ones such as the length of the linked portion. We find that the average extension of linked rings, once divided by that of a single equivalent ring, is nonmonotonic in the applied force. We show that this remarkable feature becomes more prominent as the link complexity is increased, and originates from the different stretching compliance of the linked portion and the rest of the rings' contour. By comparing the results of different pulling protocols, we also establish the best one for telling apart different types of links from their tensile response.
DOI
10.3390/polym9080327
WOS
WOS:000408747000024
Archivio
http://hdl.handle.net/20.500.11767/63579
info:eu-repo/semantics/altIdentifier/scopus/2-s2.0-85026682144
http://www.mdpi.com/2073-4360/9/8/327/pdf
Diritti
open access
Soggetti
  • Catenane

  • Linked portion

  • Mechanical stretching...

  • Semiflexible ring

  • Topological link

  • Chemistry (all)

  • Polymers and Plastics...

  • Settore FIS/03 - Fisi...

Web of Science© citazioni
19
Data di acquisizione
Jan 31, 2024
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