We make use of F-structures and technology developed by Paternain–Petean to compute minimal entropy, minimal volume, and Yamabe invariant of symplectic 4-manifolds, as well as to study their collapse with sectional curvature bounded from below.  la Gompf, we show that these invariants vanish on symplectic 4-manifolds that realize any given finitely presented group as their fundamental group. We extend to the symplectic realm a result of LeBrun which relates the Kodaira dimension with the Yamabe invariant of compact complex surfaces.