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Design of Sustainable Materials by Cross-linking a Biobased Epoxide with Keratin and Lignin

Roxana Dinu
•
Cristina Cantarutti
•
Alice Mija
2020
  • journal article

Periodico
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
Abstract
Awareness of the environmental impact of using polymeric materials obtained from petroleum is causing increased interest in sustainable materials manufacturing. Here, we present the elaboration of fully biobased materials using an aromatic epoxy resin matrix coming from wood biomass and two natural by-products, namely, keratin from chicken feathers and lignin. In situ FTIR kinetic studies show that the two natural fillers increase the conversion of the epoxide during cross-linking. This result, together with DSC studies, proves the chemical interactions between the keratin or lignin and the epoxide network. Up to 30% of these natural components could be reacted and incorporated into the epoxide with good compatibility. The thermomechanical properties of the elaborated materials are comparable to those of commercial ones.
DOI
10.1021/acssuschemeng.0c01759
WOS
WOS:000530662400029
Archivio
https://hdl.handle.net/11390/1239307
https://ricerca.unityfvg.it/handle/11390/1239307
Diritti
metadata only access
Soggetti
  • biomass waste valoriz...

  • chicken feather

  • lignin

  • epoxy thermoset

  • sustainable materials...

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