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Halloysite nanotubes/pluronic nanocomposites for waterlogged archeological wood: thermal stability and X-ray microtomography

Parisi F.
•
Bernardini F.
•
Cavallaro G.
altro
Lazzara G.
2020
  • journal article

Periodico
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
Abstract
Filling a polymer with halloysite nanotubes is considered a promising strategy to generate nanocomposites with tailored physicochemical properties. We have focused our attention on pluronic block copolymer/halloysite nanocomposites prepared by melt blending. The effect of composition on thermal stability and polymer crystallinity was investigated by thermogravimetry and differential scanning calorimetry. Electron microscopy was used to monitor the nanoparticle distribution in the polymeric matrix. The pluronic thermal stability is reduced by the clay nanoparticles. Concerning the polymer crystallinity, it is slightly decreased even if the melting temperature is lowered by halloysite. Furthermore, waterlogged archeological wood samples are consolidated using the nanotubes/pluronic nanocomposite, and the penetration of the nanocomposites into the lignin channels is confirmed by measurements based on X-ray computed microtomography.
DOI
10.1007/s10973-020-09637-4
WOS
WOS:000547257000002
Archivio
https://hdl.handle.net/11368/3118501
info:eu-repo/semantics/altIdentifier/scopus/2-s2.0-85083054189
https://link.springer.com/article/10.1007/s10973-020-09637-4
Diritti
closed access
license:copyright editore
license uri:iris.pri02
FVG url
https://arts.units.it/request-item?handle=11368/3118501
Soggetti
  • Halloysite

  • Nanocomposite

  • Nanotube

  • Pluronic

  • Restoration

  • Thermal degradation

  • Waterlogged wood

  • X-ray microtomography...

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