We report the synthesis of a TiO2 hybrid structure, consisting of a combination of nanorods and nanoparticles, subsequently treated with hydrazine to enhance the performance of photoelectrochemical (PEC) hydrogen (H2) generation. The optimized TiO2 hybrid photoanode sensitized with Quantum dots (QDs), yields a saturated photocurrent density of 4.25 mA cm−2 (at 0.8 V vs RHE), which is 172% higher than that of the reference sample. The optimized hybrid photoanode treated with hydrazine exhibits an additional 28% increase in the saturated photocurrent density, reaching 5.43 mA cm−2 with CdS QDs, and 8.12 mA cm−2 with CdS/CdSe QDs (at 0.8 V vs RHE), while maintaining 80% of the initial value of photocurrent density, after 2 h of continuous one sun illumination (AM 1.5 G, 100 mW cm−2). We used Density Functional Theory with Hubbard energy correction (DFT + U) calculations to describe the mechanism that underpins this significant improvement. DFT + U results highlighted that the concentration of the hydrazine treatment plays a crucial role and affects the sites (surface or interstitial) where nitrogen may be present. This eventually affects the recombination centers within the hybrid photoanode. Thus, the results of this work define a promising strategy to optimize the morphology of the hybrid photoanodes via hydrazine surface engineering to fabricate efficient and stable PEC water splitting devices for H2 generation.
