In binary star systems, mass transfer can spin up the accretor, possibly leading to efficient chemical mixing and chemically quasi-homogeneous evolution (CHE). Here, we explore the effects of accretion-induced CHE on both stellar populations and their compact binary remnants with the state-of-the-art population synthesis code SEVN. We find that CHE efficiently enhances the formation of Wolf–Rayet stars (WRs) from secondary stars, which are spun up by accretion, while simultaneously preventing their evolution into red supergiant stars (RSGs). Including CHE in our models increases the fraction of WRs in our stellar sample by nearly a factor of ≈3 at low metallicity (Z = 0.001). WRs formed through CHE are, on average, more massive and luminous than those formed without CHE. Most WRs formed via CHE end their life as black holes. As a direct consequence, the CHE mechanism enhances the formation of binary black holes (BBHs) and black hole-neutron star (BHNS) systems, while also quenching the production of binary neutron stars (BNSs). However, CHE significantly quenches the merger rate of BBHs, BHNSs, and BNSs at low metallicity (Z ≤ 0.004), because most binary compact objects formed via CHE have large orbital periods. For instance, the number of BBH and BHNS mergers decreases by one order of magnitude at Z = 0.004 in the CHE model compared to the standard scenario. Finally, we find that secondary stars experiencing CHE frequently produce the most massive compact object in the binary system. In BHNSs, this implies that the black hole progenitor is the secondary star. Conversely, BBHs formed through accretion-induced CHE likely have asymmetric black hole components, but only a negligible fraction of these asymmetric systems ultimately merge within an Hubble time.
