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The four-member square scheme in cyclic voltammetry: general solution for nernstian electron transfers

BALDUCCI, GABRIELE
•
COSTA, GIACOMO
1993
  • journal article

Periodico
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
Abstract
A general solution of the four-member square scheme under cyclic voltammetric conditions is presented. The diffusional problem is converted into a system of integral equations, which can be solved numerically, giving 'individual' currents. The heterogeneous electron transfer steps are assumed to be nernstian, while no limitations on the magnitude of the kinetic constants of the homogeneous chemical reactions are imposed.
DOI
10.1016/0022-0728(93)80142-5
WOS
WOS:A1993KZ57300024
SCOPUS
2-s2.0-0013145887
Archivio
http://hdl.handle.net/11368/2834840
Diritti
metadata only access
Soggetti
  • Chemical Engineering ...

  • Analytical Chemistry

  • Electrochemistry

Web of Science© citazioni
13
Data di acquisizione
Mar 22, 2024
Visualizzazioni
2
Data di acquisizione
Apr 19, 2024
Vedi dettagli
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