Logo del repository
  1. Home
 
Opzioni

Statistical field theory with constraints: Application to critical Casimir forces in the canonical ensemble

Gross, Markus
•
Dietrich, S.
•
Gambassi, Andrea
2017
  • journal article

Periodico
PHYSICAL REVIEW. E
Abstract
The effect of imposing a constraint on a fluctuating scalar order parameter field in a system of finite volume is studied within statistical field theory. The canonical ensemble, corresponding to a fixed total integrated order parameter (e.g., the total number of particles), is obtained as a special case of the theory. A perturbative expansion is developed which allows one to systematically determine the constraint-induced finite-volume corrections to the free energy and to correlation functions. In particular, we focus on the Landau-Ginzburg model in a film geometry (i.e., in a rectangular parallelepiped with a small aspect ratio) with periodic, Dirichlet, or Neumann boundary conditions in the transverse direction and periodic boundary conditions in the remaining, lateral directions. Within the expansion in terms of e = 4 − d, where d is the spatial dimension of the bulk, the finite-size contribution to the free energy of the confined system and the associated critical Casimir force are calculated to leading order in e and are compared to the corresponding expressions for an unconstrained (grand canonical) system. The constraint restricts the fluctuations within the system and it accordingly modifies the residual finite-size free energy. The resulting critical Casimir force is shown to depend on whether it is defined by assuming a fixed transverse area or a fixed total volume. In the former case, the constraint is typically found to significantly enhance the attractive character of the force as compared to the grand canonical case. In contrast to the grand canonical Casimir force, which, for supercritical temperatures, vanishes in the limit of thick films, in the canonical case with fixed transverse area the critical Casimir force attains for thick films a negative value for all boundary conditions studied here. Typically, the dependence of the critical Casimir force both on the temperature-like and on the field-like scaling variables is different in the two ensembles.
DOI
10.1103/PhysRevE.96.022135
WOS
WOS:000407555400003
Archivio
http://hdl.handle.net/20.500.11767/59025
info:eu-repo/semantics/altIdentifier/scopus/2-s2.0-85028743507
https://link.aps.org/doi/10.1103/PhysRevE.96.022135
https://arxiv.org/abs/1705.11012
Diritti
closed access
Soggetti
  • Settore FIS/02 - Fisi...

  • Settore FIS/03 - Fisi...

Web of Science© citazioni
13
Data di acquisizione
Mar 27, 2024
Visualizzazioni
3
Data di acquisizione
Apr 19, 2024
Vedi dettagli
google-scholar
Get Involved!
  • Source Code
  • Documentation
  • Slack Channel
Make it your own

DSpace-CRIS can be extensively configured to meet your needs. Decide which information need to be collected and available with fine-grained security. Start updating the theme to match your nstitution's web identity.

Need professional help?

The original creators of DSpace-CRIS at 4Science can take your project to the next level, get in touch!

Realizzato con Software DSpace-CRIS - Estensione mantenuta e ottimizzata da 4Science

  • Impostazioni dei cookie
  • Informativa sulla privacy
  • Accordo con l'utente finale
  • Invia il tuo Feedback