Unusual disordering processes of oxygen overlayers on Rh(111): A combined diffraction study using thermal He atoms and low-energy electrons

The temperature-dependent behavior of the Rh(111)-(2X2)-10 phase was investigated by He-atom scattering (HAS) and low-energy electron diffraction. The adsorption system undergoes an order-disorder phase transition at T-c=280+/-5 K, with critical exponents found to be consistent with the four-state Potts model. Beyond the phase transition the HAS specular peak intensity exhibits a strong and reversible increase. This finding points toward a reduction of the surface charge-density corrugation induced by the phase transition itself. Around 160 K, hydrogen adsorbed on the Rh(111)-(2X2)-10 surface reacts with oxygen to form water, and drives the overlayer in an out-of-equilibrium condition which is characterized by a dramatic domain-wall proliferation.