A velocity map imaging/ion time-of-flight spectrometer designed specifically for pump–probe experiments combining synchrotron and laser radiations is described. The in-house built delay line detector can be used in two modes: the high spatial resolution mode and the coincidence mode. In the high spatial resolution mode a kinetic energy resolution of 6% has been achieved. The coincidence mode can be used to improve signal-to-noise ratio for the pump–probe experiments either by using a gate to count electrons only when the laser is present or by recording coincidences with the ion formed in the ionization process.
