The evolution of papermaking from XII century, in Europe, was characterized by continuous changes of fibrous and non-fibrous materials as cellulose, wood pulp, sizing agents, fillers and
coatings. In this study, the composition of many ancient paper documents is analysed by means of
non-destructive Fourier Transform Infrared Spectroscopy (FTIR) in order to identify the main
components of paper and to evaluate the presence of other compounds. The substances that cannot
be detected by FTIR analysis are also underlined. The goal of this work is to set up an FTIR
database for diagnostic purposes and to identify optimal spectral ranges useful for chemometric
analyses.
