Lateral quantum confinement is of great interest in tuning the electronic properties of graphene-based nanostructures, making them suitable for technological applications. In principle, these properties might be controlled through the edge topology: for example, zigzag nanoribbons are predicted to have spin-polarized edge states. The practical realization of these structures is of utmost importance in fully harnessing the electronic properties of graphene. Here, the formation of regular, 1.4 nm wide ribbon-like graphene structures with zigzag edges are reported, showing 1D electronic states. It is found that these “pseudo-ribbons” embedded in single-layer graphene supported on Ni(100) can spontaneously form upon carbon segregation underneath 1D graphene moiré domains, extending hundreds of nanometers in length. On the basis of both microscopy/spectroscopy/diffraction experiments and theoretical simulations, it is shown that these structures, even though seamlessly incorporated in a matrix of strongly interacting graphene, exhibit electronic properties closely resembling those of zigzag nanoribbons.
