Alternative intermediates for glycerol valorization: iridium-catalyzed formation of acetals and ketals
Crotti C.
•
FARNETTI, ERICA
•
Guidolin N.
2010
Periodico
GREEN CHEMISTRY
Abstract
The organoiridium derivatives [Cp*IrCl2]2 (Cp* = pentamethylcyclopentadienyl) and [Cp*Ir(Bu2-NHC)Cl2] (Bu2-NHC = 1,3-di-n-butylimidazolylidene) catalyze glycerol acetalization with several ketones and aldehydes, as well as transacetalization.
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