Among superhydrophobic materials, non-wettable textiles are probably the ones that come in contact or interact with the human body most frequently. Hence, textile treatments for water or oil repellency should be non-toxic, biocompatible, and comply with stringent health standards. Moreover, considering the volume of the worldwide textile industry, these treatments should be scalable, sustainable, and eco-friendly. Due to this awareness, more and more non-wettable textile treatments with eco-friendly processes and green or non-toxic chemicals are being adopted and reported. Although fluorinated alkylsilanes or fluorinated polymers with C8 chemistry (with ≥ 8 fluorinated carbon atoms) are the best performing materials to render textiles water or oil repellent, they pose substantial health and environmental problems and are being banned. For this reason, water/solvent-borne, C8-free vehicles for non-wettable treatment formulations are probably the only ones that can have commercialization prospects. Hence, researchers have come up with a variety of new, non-toxic, green formulations and materials to render fabrics liquid repellent that constitute the focus of this review paper. As such, this review article discusses and summarizes recent developments and techniques on various sustainable superhydrophobic treatments for textiles, with comparable performance and durability to formulations based on fluorinated C8 compounds. The current state-of-the-art technologies, potential commercialization prospects, and relevant limitations are discussed and summarized with examples. The review also attempts to indicate promising future strategies and new materials that can transform the process for non-wettable textiles into an all-sustainable technology.
