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Clustering, conductor-insulator transition and phase separation of an ultrasoft model of electrolytes

Coslovich D
•
Hansen JP
•
Kahl G
2011
  • journal article

Periodico
SOFT MATTER
Abstract
We investigate the clustering and phase separation of a model of ultrasoft, oppositely charged macroions by a combination of Monte Carlo and Molecular Dynamics simulations. Static and dynamic diagnostics, including the dielectric permittivity and the electric conductivity of the model, show that ion pairing induces a sharp conductor-insulator transition at low temperatures and densities, which impacts the separation into dilute and concentrated phases below a critical temperature. Preliminary evidence is presented for a possible tricritical nature of the phase diagram of the model.
DOI
10.1039/c0sm01090a
WOS
WOS:000287588800022
Archivio
http://hdl.handle.net/11368/2969147
info:eu-repo/semantics/altIdentifier/scopus/2-s2.0-79951907943
Diritti
metadata only access
Scopus© citazioni
22
Data di acquisizione
Jun 14, 2022
Vedi dettagli
Web of Science© citazioni
21
Data di acquisizione
Mar 19, 2024
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