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Microwave-assisted green oxidation of alcohols with hydrogen peroxide catalyzed by iron complexes with nitrogen ligands

Cozzi, Irene Sofia
•
Crotti, Corrado
•
Farnetti, Erica
2018
  • journal article

Periodico
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Abstract
Oxidation of primary and secondary alcohols, including two diols and glycerol, with H2O2 was catalyzed by the iron(II) complexes [FeL3](OTf)2 (L 1⁄4 2,20-bipyridine, 2,20-bipyrimidine, 1,10-phenanthroline and substituted derivatives) and [FeL2](OTf)2 (L 1⁄4 bis(2-pyridinylmethyl)amine, 2,6-di(2-pyridyl)pyridine). The reactions were performed in acetonitrile, water or mixed solvent (typically water/acetonitrile 4:1) in a microwawe reactor at low power. Effect of addition of a cocatalyst, which in some cases improved the yields of the catalytic reaction, was investigated by means of NMR and UVeVisible techniques.
DOI
10.1016/j.jorganchem.2018.10.003
WOS
WOS:000449711200005
Archivio
http://hdl.handle.net/11368/2930547
info:eu-repo/semantics/altIdentifier/scopus/2-s2.0-85054753935
https://www.sciencedirect.com/science/article/pii/S0022328X1830559X
Diritti
closed access
license:copyright editore
license:copyright editore
FVG url
https://arts.units.it/request-item?handle=11368/2930547
Soggetti
  • Alcohol

  • Iron catalyst

  • Microwave

  • Nitrogen ligand

  • Oxidation

  • Biochemistry

  • Physical and Theoreti...

  • Organic Chemistry

  • Inorganic Chemistry

  • Materials Chemistry25...

Web of Science© citazioni
6
Data di acquisizione
Mar 26, 2024
Visualizzazioni
6
Data di acquisizione
Apr 19, 2024
Vedi dettagli
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