In this paper, first we consider the existence and non-existence of Einstein metrics on the topological 4-manifolds $3\mathbb{CP}^2 # k \bar{\mathbb{CP}}^2$ (for k∈11,13,14,15,16,17,18) by using the idea of R\u{a}sdeaconu and \c{S}uvaina (2009) and the constructions in Park, Park, and Shin (arXiv:0906.5195v2) and in Park, Park, and Shin (2009). Then, we study the existence or non-existence of non-singular solutions of the normalized Ricci flow on the exotic smooth structures of these topological manifolds by employing the obstruction developed in Ishida (2008).