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Effective forces in square well and square shoulder fluids

Fiocco D.
•
PASTORE, GIORGIO
•
Foffi G.
2010
  • journal article

Periodico
JOURNAL OF PHYSICAL CHEMISTRY. B, CONDENSED MATTER, MATERIALS, SURFACES, INTERFACES & BIOPHYSICAL
Abstract
We derive an analytical expression for the effective force between a pair of macrospheres immersed in a sea of microspheres, in the case where the interaction between the two unlike species is assumed to be a square well or a square shoulder of given range and depth (or height). This formula extends a similar one developed in the case of hard core interactions only. Qualitative features of such effective force and the resulting phase diagrams are then analyzed in the limit of no interaction between the small particles. Approximate force profiles are then obtained by means of integral equation theories (PY and HNC) combined with the superposition approximation and compared with exact ones from direct Monte Carlo simulations.
DOI
10.1021/jp105145x
WOS
WOS:000281753900016
Archivio
http://hdl.handle.net/11368/2310679
info:eu-repo/semantics/altIdentifier/scopus/2-s2.0-79951866786
Diritti
metadata only access
Soggetti
  • Teoria dello stato li...

  • Colloidi

  • Modelli di interazion...

Web of Science© citazioni
9
Data di acquisizione
Mar 10, 2024
Visualizzazioni
8
Data di acquisizione
Apr 19, 2024
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