Rheometrical techniques can be profitably used for polysaccharide matrices in order to evaluate their suitability for the preparation of stable cosmetic O/W emulsions. In particular, the rheological properties of aqueous scleroglucan systems were investigated under continuous and oscillatory shear conditions in a polymer concentration range embracing the sol/gel transition. The effects due to the addition of two different surfactants were examined at constant polymer concentration. Polysaccharide–surfactant interactions leading to complex formation were detected also through rheology. The combined action of both nonionic and cationic surfactants in the polymer solution was examined demonstrating the beneficial effects produced on the mechanical properties of the polymer matrix by the coexistence of both surfactants. Such beneficial effects are confirmed by the stability and rheology shown by the emulsions prepared.
