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The restricted primitive model of ionic fluids with nonadditive diameters

FANTONI, RICCARDO
•
PASTORE, GIORGIO
2013
  • journal article

Periodico
EUROPHYSICS LETTERS
Abstract
The restricted primitive model with nonadditive hard-sphere diameters is shown to have interesting and peculiar clustering properties. We report accurate calculations of the cluster concentrations. Implementing efficient and ad hoc Monte Carlo algorithms we determine the effect of nonadditivity on both the clustering and the gas-liquid binodal. For negative nonadditivity, tending to the extreme case of completely overlapping unlike ions, the prevailing clusters are made of an even number of particles having zero total charge. For positive nonadditivity, the frustrated tendency to segregation of like particles and the reduced space available to the ions favors percolating clusters at high densities.
DOI
10.1209/0295-5075/101/46003
WOS
WOS:000315999100021
Archivio
http://hdl.handle.net/11368/2660513
info:eu-repo/semantics/altIdentifier/scopus/2-s2.0-84874834405
Diritti
metadata only access
Soggetti
  • primitive model

  • ionic fluid

  • non-additive diameter...

Web of Science© citazioni
8
Data di acquisizione
Mar 10, 2024
Visualizzazioni
2
Data di acquisizione
Apr 19, 2024
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