Calculations of the discrete Cl 1s and 2p excitation spectra of HCl are performed employing accurate ab-initio
. . Configuration Interaction CI and Density Functional DF approaches. The core excited spectra above edge are described
with a new DF method based on a one-centre approximation. The highly correlated quasi-degenerate perturbation scheme
gives results in excellent accord with experimental data and allows a definite assignment of the Rydberg excited states below
edge. The simpler 1h–1p CI scheme shows some deficiencies essentially attributed to the use of inadequate orbitals,
although it appears adequate for a qualitative description of the spectra. The DF approach provides dependable results for the
lower-energy states of the discrete spectra while some limitations affect the present description of the higher Rydberg states.
Good agreement with experimental data is obtained for the calculated cross-section profiles relative to the Cl 1s and 2p
photoionization. Also the theoretical asymmetry parameter profiles are analysed. q1998 Elsevier Science B.V. All rights
reserved.
