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On the rate determining step in the reduction of CeO2-ZrO2 mixed oxides

FORNASIERO, Paolo
•
KASPAR, JAN
•
GRAZIANI, MAURO
1999
  • journal article

Periodico
APPLIED CATALYSIS. B, ENVIRONMENTAL
Abstract
The temperature programmed reduction (TPR) of Ce0.5Zr0.5O2 mixed oxide is investigated by using 1H2/Ar and 2H2/Ar mixtures as reducing agents. For low temperature reduction (below 700 K), no differentiation of the TPR profiles between the two reductants is observed. This suggests that activation of the reducing agents, e.g. surface steps, is not rate limiting this reduction process under the TPR conditions. The temperature programmed reduction (TPR) of Ce0.5Zr0.5O2 mixed oxide is investigated by using 1H2/Ar and 2H2/Ar mixtures as reducing agents. For low temperature reduction (below 700 K), no differentiation of the TPR profiles between the two reductants is observed. This suggests that activation of the reducing agents, e.g. surface steps, is not rate limiting this reduction process under the TPR conditions.
DOI
10.1016/S0926-3373(99)00038-7
WOS
WOS:000081731400003
Archivio
http://hdl.handle.net/11368/1694232
info:eu-repo/semantics/altIdentifier/scopus/2-s2.0-0345280783
Diritti
metadata only access
Soggetti
  • redox propertie

  • ceria-zirconia mixed ...

  • kinetic

  • temperature programme...

Web of Science© citazioni
94
Data di acquisizione
Mar 27, 2024
Visualizzazioni
2
Data di acquisizione
Apr 19, 2024
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