We investigate the dynamical deconfinement transition driven by excitations in a long-range Ising model. At low temperatures, spatially separated pairs of domain wall kinks are bound by the confining potential and exhibit uncorrelated Bloch oscillations in time. This picture is analogous to bound mesons in quark confinement. As the temperature increases, the meson picture breaks down as the domain wall kinks in proximity interact and disperse, leading to an extended deconfined regime. In this paper, we characterize the deconfinement transition with signatures observed in the average density of domain wall kinks and nonequilibrium changes in its fluctuation. Our findings provide insights into the mechanisms of confinement and deconfinement in long-range spin models, thus opening avenues for further exploration and experimental verification.