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Partial photoionization cross sections of C60 and C70: a gas versus adsorbed phase comparison

Korica S.
•
Reinköster A.
•
Braune M.
altro
Becker U.
2010
  • journal article

Periodico
SURFACE SCIENCE
Abstract
We have performed high resolution measurements of the photoelectrons emitted from the valence shell of C60 and C70, in the gas phase and adsorbed phase on a metal surface, in order to derive branching ratios and the partial photoionization cross sections of the two highest occupied molecular orbitals, HOMO and HOMO- 1. The comparison between the gas phase and the adsorbed phase shows an interesting and unexpected difference that can be attributed to a small orbital shift in solid C70. Density Functional Theory calculations within the Local Density Approximation (LDA) show good agreement for both data sets and give a plausible explanation for the observed difference
DOI
10.1016/j.susc.2010.07.031
WOS
WOS:000283014500021
Archivio
http://hdl.handle.net/11368/2303148
info:eu-repo/semantics/altIdentifier/scopus/2-s2.0-77957149920
Diritti
metadata only access
Soggetti
  • Synchrotron radiation...

Web of Science© citazioni
12
Data di acquisizione
Mar 26, 2024
Visualizzazioni
1
Data di acquisizione
Apr 19, 2024
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