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Entropy of self-avoiding branching polymers: Mean-field theory and Monte Carlo simulations

Marcato, Davide
•
Giacometti, Achille
•
Maritan, Amos
•
Rosa, Angelo
2025
  • journal article

Periodico
THE JOURNAL OF CHEMICAL PHYSICS
Abstract
We study the statistics of branching polymers with excluded-volume interactions, by modeling them as single self-avoiding trees on a generic regular periodic lattice with coordination number q. Each lattice site can be occupied at most by one tree node, and the fraction of occupied sites can vary from dilute to dense conditions. By adopting the statistics of rooted-directed trees as a proxy for that of undirected trees without internal loops and by an exact mapping of the model into a field theory, we compute the entropy and the mean number of branch nodes within a mean-field approximation and in the thermodynamic limit. In particular, we find that the mean number of branch nodes is independent of both the lattice details and the lattice occupation, depending only on the associated chemical potential. Monte Carlo simulations in d = 2, 3, 4 provide evidence of the remarkable accuracy of the mean-field theory, more accurate for higher dimensions.
DOI
10.1063/5.0287899
Archivio
https://hdl.handle.net/20.500.11767/150851
info:eu-repo/semantics/altIdentifier/scopus/2-s2.0-105018268937
https://arxiv.org/abs/2506.22315
https://ricerca.unityfvg.it/handle/20.500.11767/150851
Diritti
closed access
license:creative commons
license uri:http://creativecommons.org/licenses/by-nc/4.0/
Soggetti
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