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Mechanochemical reactivity inhibited, prohibited and reversed by liquid additives: examples from crystal-form screens

Arhangelskis, Mihails
•
BuÄ ar, Dejan-KreÅ¡imir
•
Bordignon, Simone
altro
Hasa, Dritan
2021
  • journal article

Periodico
CHEMICAL SCIENCE
Abstract
We demonstrate that liquid additives can exert inhibitive or prohibitive effects on the mechanochemical formation of multi-component molecular crystals, and report that certain additives unexpectedly prompt the dismantling of such solids into physical mixtures of their constituents. Computational methods were employed in an attempt to identify possible reasons for these previously unrecognised effects of liquid additives on mechanochemical transformations.
DOI
10.1039/D0SC05071G
WOS
WOS:000627505700018
Archivio
http://hdl.handle.net/11368/2981793
info:eu-repo/semantics/altIdentifier/scopus/2-s2.0-85102445234
https://pubs.rsc.org/en/content/articlelanding/2021/sc/d0sc05071g#!divAbstract
Diritti
open access
license:creative commons
license uri:http://creativecommons.org/licenses/by-nc/4.0/
FVG url
https://arts.units.it/bitstream/11368/2981793/1/d0sc05071g.pdf
Soggetti
  • mechanochemistry

  • liquid-assisted grind...

  • cocrystal

  • polymorphism

  • solid-state.

Web of Science© citazioni
25
Data di acquisizione
Mar 24, 2024
Visualizzazioni
4
Data di acquisizione
Apr 19, 2024
Vedi dettagli
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