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"Magic" Surface Clustering of Borazines Driven by Repulsive Intermolecular Forces

Kervyn S.
•
Kalashnyk N.
•
Riello M.
altro
BONIFAZI, DAVIDE
2013
  • journal article

Periodico
ANGEWANDTE CHEMIE. INTERNATIONAL EDITION
Abstract
It's a kind of magic: Hydroxy pentaaryl borazine molecules self-assemble into small clusters (see structure) on Cu(111) surfaces, whereas with symmetric hexaaryl borazine molecules large islands are obtained. Simulations indicate that the observed “magic” cluster sizes result from long-range repulsive Coulomb forces arising from the deprotonation of the B[BOND]OH groups of the hydroxy pentaaryl borazine.
DOI
10.1002/anie.201300948
WOS
WOS:000328708300006
SCOPUS
2-s2.0-84880090103
Archivio
http://hdl.handle.net/11368/2768359
Diritti
metadata only access
Soggetti
  • organic supramolecula...

Web of Science© citazioni
33
Data di acquisizione
Mar 23, 2024
Visualizzazioni
2
Data di acquisizione
Apr 19, 2024
Vedi dettagli
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