NOE and PGSE NMR experiments provide crucial information for the structural characterization of non-covalent intimate adducts in solution. The possible presence and the favorite relative orientation of the interacting units can be deduced from NOE results, while the size of the non-covalent adducts can be estimated through PGSE measurements. The complementarity of the two methodologies has been successfully used to investigate transition metal complex ion pairs and, to a lesser extent, intermolecular adducts. The main results concerning the solution structures of non-covalent inorganic adducts are reported and compared with those in the solid state and those from theoretical calculations.
