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Phase diagram and structural properties of a simple model for one-patch particles

GIACOMETTI A
•
LADO F
•
LARGO J
altro
SCIORTINO F.
2009
  • journal article

Periodico
THE JOURNAL OF CHEMICAL PHYSICS
Abstract
We study the thermodynamic and structural properties of a simple, one-patch fluid model using the reference hypernetted-chain RHNC integral equation and specialized Monte Carlo simulations. In this model, the interacting particles are hard spheres, each of which carries a single identical, arbitrarily oriented and attractive circular patch on its surface; two spheres attract via a simple square-well potential only if the two patches on the spheres face each other within a specific angular range dictated by the size of the patch. For a ratio of attractive to repulsive surface of 0.8, we construct the RHNC fluid-fluid separation curve and compare with that obtained by Gibbs ensemble and grand canonical Monte Carlo simulations. We find that RHNC provides a quick and highly reliable estimate for the position of the fluid-fluid critical line. In addition, it gives a detailed though approximate description of all structural properties and their dependence on patch size.
DOI
10.1063/1.3256002
WOS
WOS:000271664500020
Archivio
http://hdl.handle.net/11368/2286472
info:eu-repo/semantics/altIdentifier/scopus/2-s2.0-70449378633
Diritti
metadata only access
Soggetti
  • patchy colloids

Web of Science© citazioni
40
Data di acquisizione
Mar 17, 2024
Visualizzazioni
1
Data di acquisizione
Apr 19, 2024
Vedi dettagli
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